About the iron carbonyl complex with C60and C70fullerene: [Fe(CO)4(η2C60)] and [Fe(CO)4(η2C70)]
The iron carbonyl complexes with C60 and C70 fullerenes were synthesized in high yield by photochemical irradiation of solutions of C60 and C70 in presence of Fe(CO)5. The resulting complexes were studied by FT-IR, Raman and electronic absorption spectroscopy. All the data are consistent with the structures [Fe(CO)4(η2C60)] and [Fe(CO)4(η2C70)]
Garcia-hernandez, D. A. et al.
Fecha de publicación:
3
2016