Temperature inversion layers are predicted to be present in ultra-hot giant planet atmospheres. Although such inversion layers have recently been observed in several ultra-hot Jupiters, the chemical species responsible for creating the inversion remain unidentified. Here, we present observations of the thermal emission spectrum of an ultra-hot Jupiter, WASP-189b, at high spectral resolution using the HARPS-N spectrograph. Using the cross-correlation technique, we detect a strong Fe I signal. The detected Fe I spectral lines are found in emission, which is direct evidence of a temperature inversion in the planetary atmosphere. We further performed a retrieval on the observed spectrum using a forward model with an MCMC approach. When assuming a solar metallicity, the best-fit result returns a temperature of 4320-100+120 K at the top of the inversion, which is significantly hotter than the planetary equilibrium temperature (2641 K). The temperature at the bottom of the inversion is determined as 2200-800+1000 K. Such a strong temperature inversion is probably created by the absorption of atomic species like Fe I.

The combined residual spectrum in Fig. B.1 is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/cat/J/A+A/640/L5