In recent years, about 150 low-mass white dwarfs (WDs), typically with masses below 0.4 M⊙, have been discovered. The majority of these low-mass WDs are observed in binary systems as they cannot be formed through single-star evolution within Hubble time. In this work, we present a comprehensive analysis of the double low-mass WD eclipsing binary system J2102−4145. Our investigation encompasses an extensive observational campaign, resulting in the acquisition of approximately 28 h of high-speed photometric data across multiple nights using NTT/ULTRACAM, SOAR/Goodman, and SMARTS-1m telescopes. These observations have provided critical insights into the orbital characteristics of this system, including parameters such as inclination and orbital period. To disentangle the binary components of J2102−4145, we employed the XTGRID spectral fitting method with GMOS/Gemini-South and X-shooter data. Additionally, we used the PHOEBE package for light curve analysis on NTT/ULTRACAM high-speed time-series photometry data to constrain the binary star properties. Our analysis unveils remarkable similarities between the two components of this binary system. For the primary star, we determine Teff,1 = 13 688−72+65 K, log g1 = 7.36 ± 0.01, R1 = 0.0211 ± 0.0002 R⊙, and M1 = 0.375 ± 0.003 M⊙, while, the secondary star is characterised by Teff,2 = 12952−66+53 K, log g2 = 7.32 ± 0.01, R2 = 0.0203−0.0003+0.0002 R⊙, and M2 = 0.314 ± 0.003 M⊙. Furthermore, we found a notable discrepancy between Teff and R of the less massive WD, compared to evolutionary sequences for WDs from the literature, which has significant implications for our understanding of WD evolution. We discuss a potential formation scenario for this system which might explain this discrepancy and explore its future evolution. We predict that this system will merge in ∼800 Myr, evolving into a helium-rich hot subdwarf star and later into a hybrid He/CO WD.