We present an astrometric catalogue of positions and proper motions derived from the Carte du Ciel plates of the San Fernando zone, photographic material with a mean epoch 1901.4 with a limiting magnitude V ˜ 15. Digitization has been made using a conventional flatbed scanner. Special techniques have been developed to handle the combination of plate material and the large distortion introduced by the scanner. A variety of post-scan corrections are shown to be necessary. The equatorial coordinates are on the ICRS system defined by Tycho-2. Comparison with the reference catalog indicates external errors of 0''.2. The UCAC2 Catalogue was used as second-epoch positions to derive proper motions with a mean accuracy of 1.2 mas/year for the proper motions for well-measure stars.