The stellar spectroscopic sequence has now been extended into very cool objects bridging the gap between low-mass stars and classical planets. Those objects, called Y dwarfs, are the coolest substellar objects known to date with temperatures below 500 Kelvins. We obtained z-band far-red imaging for six Y dwarfs and a T9+Y0 binary with GTC/OSIRIS to characterise their spectral energy distribution. This photometric dataset represent the first optical detection of Y dwarfs. I will present the z-band photometry, optical-to-infrared colours, and proper motions of these Y dwarfs. I will discuss the larger dispersion in the optical-to-infrared colours of Y dwarfs than in warmer brown dwarfs, which may originate from presence of sulfide clouds, the depletion of alcalines, and/or gravity effects.